Titlebook: Sulfur Dioxide Insertion Reactions for Organic Synthesis; Danqing Zheng,Jie Wu Book 2017 The Author(s) 2017 Sulfur dioxide insertion.Sulfo

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Book 2017development of synthetic methods through the insertion of sulfur dioxide. Depending on the nature of the transformation, these reactions are classified into four types: (i) pericyclic reactions; (ii) nucleophilic addition with organometallic reagents; (iii) transition metal catalysis; and (iv) free

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Sulfur Dioxide Insertion Reactions,types of transformation, these reactions are classified into four parts: (i) nucleophilic addition with organometallic reagents; (ii) transition metal catalysis; (iii) free radical reactions; and (iv) pericyclic reactions. These processes provide an efficient and practical route for the construction of sulfonyl-containing compounds.

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Sulfur Dioxide Surrogates,s. To date, several sulfur dioxide surrogates have been developed and proved to be efficient in the processes of sulfur dioxide insertion. Among them, DABCO·(SO.). (named DABSO) and potassium metabisulfite (K.S.O.) are two of the most commonly used sulfur dioxide surrogates, which have been identifi

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Sulfur Dioxide Insertion Reactions,e reactions involved with the insertion of sulfur dioxide, with an emphasis on recent advances achieved by the application of sulfur dioxide surrogates. We will describe representative examples following the ideas of reaction design, and present the general experimental procedures. According to the

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Sulfur Dioxide Surrogates, DABCO·(SO.). (named DABSO) and potassium metabisulfite (K.S.O.) are two of the most commonly used sulfur dioxide surrogates, which have been identified and documented in various transformations. In this chapter, we will introduce these sulfur dioxide surrogates, with an emphasis on those utilized in sulfur dioxide insertion reactions.