Titlebook: New Polymeric Materials Based on Element-Blocks; Yoshiki Chujo Book 2019 Springer Nature Singapore Pte Ltd. 2019 Functional polymer.Organi

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Element-Block Polymeric Materials Based on Cage Silsesquioxane Frameworksth a completely condensed POSS. Difunctional POSS monomers, which were prepared by a selective corner-opening reaction and a subsequent corner-capping reaction, significantly reduce their crystallinity in comparison with those of monofunctionalized T. cages. Several examples for polymerization of the difunctional POSS monomers are described.

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Polyphosphazenes as an Example of the Element-Blocks Approach to New Materialshe employment of reagent size and reactivity to control polymer properties and emphasize specific uses. Applications have been developed for these polymers as elastomers, thermoplastics, biostable or bioerodible medical materials, fire-resistant lithium battery electrolytes, films, or foams, and gas and liquid separation membranes.

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Organic-Inorganic Hybrid Material with Surface-Modified Zirconia Nanoparticles as Element Blocksve surface modifications of zirconia nanoparticles were successfully developed by two treatments of (1) with silane coupling agent and isocyanate compound and (2) with dual-site silane coupling agent. These dispersions can be applied to prepare the high refractive index thin films.

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Element-Block Materials: New Concept for the Development of Advanced Hybrids and Inorganic Polymersonents such as designability and good processability and inorganic elements can be expected. However, there are several difficulties in combination with organic and inorganic components due to intrinsic low compatibility between organic and inorganic components. Although organic-inorganic hybrids ha

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Si-, Ge-, and Sn-Bridged Biaryls as π-Conjugated Element Blockslocks having condensed tricyclic systems with silole, germole, and stannole as the center ring. These bridged biaryls exhibit interesting properties arising from the characteristics of both the biaryl units and the bridging elements. In this chapter, recent development in functional organic material