Titlebook: New Aspects in Phosphorus Chemistry I; Jean-Pierre Majoral (Directeur de Recherche) Book 2002 Springer-Verlag Berlin Heidelberg 2002 Anorg

BOOM

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New Trends in Phosphametallocene Chemistry,metal complexes and their ?.-transition metal complexes can act as π-acceptor ligands for coordination chemistry. In this review three interrelated areas exploiting these characteristics are presented. They comprise new structures and reagents based upon main-group phospholyl complexes, the incorpor

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小卒

New Chiral Organophosphorus Catalysts in Asymmetric Synthesis,ts in this area and more precisely in the kinetic resolution of secondary alcohols, the enantioselective borane reduction of ketones, and in the asymmetric C-C bond formation with the introduction of asymmetric two-center catalysts.

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Metal-Mediated Degradation and Reaggregation of White Phosphorus,e underlying principles to account for the activation and stepwise fragmentation of this molecule in the presence of transition metal complexes are presented with emphasis given to mechanistic aspects. A collection of .P-NMR spectral data for the known polyphosphorus P. compounds (x ≤ 4) is also pre

indignant

New Inorganic Polymers Containing Phosphorus,ents in the area of linear inorganic polymers based on phosphorus are reviewed. The 1990s saw the development of a number hybrid polymer systems where elements such as carbon and sulfur were incorporated into polymer backbones along with phosphorus and nitrogen. Many of these novel materials were sy

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泄露

Recent Progress in Carbonylphosphonate Chemistry, and .-ketophosphonates, including two classes of trifunctional carbonyl phosphonates, .-ketophosphonoglyoxylates and carbonylbisphosphonates. These compounds (and analogous derivatives) exhibit distinctive, multiple chemical properties reflecting in part the mutual intereaction of their neighboring

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