Titlebook: Matrix Isolation Spectroscopy; A. J. Barnes,W. J. Orville-Thomas,R. Gaufrès Book 1981 D. Reidel Publishing Company, Dordrecht, Holland 198

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Generation and Trapping of Unstable Solutes in Low Temperature Matricesmatrix isolation now exist which utilise solely the narrow bandwidths and the lack of hot bands and rotational fine structure, e.g. the analysis of gas mixtures (4), this chapter aims to give an overview of the experimental approaches used in the generation, trapping and characterising of unstable s

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High Pressure Studiesnse phases. Indeed, matrix study is a particular case of dense phases investigations. In both techniques, the spectroscopist is mainly interested in observing the spectral perturbations due to the interactions between the active molecule and its environment. In both cases, one is facing the same phy

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Matrix Effects Studied by Electron Spin Resonance Spectroscopys of electronic structure revealed by e.s.r. spectra were considered in the preceding Review (1), and have been extensively discussed elsewhere (1–3), I consider primarily the specific effects of the matrix on the properties of the trapped radicals. This includes orientational factors, dynamic chang

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Vibrational Band Intensities In Matricesn notorious for errors of as much as a factor of ten; even now one is not surprised too much to find that one’s new measurements differ by a factor of two from previous results in the literature. Nevertheless, the situation is improving rapidly and it is now possible for two carefully conducted meas

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Vibrational Spectra of Matrix Isolated Gaseous Ternary Oxidesg other physico-chemical studies, has been employed extensively for the study of perrhenates, chromates, molybdates, tungstates, vanadates, metaborates, nitrates, phosphates, sulfates of alkali and alkaline-earth metals and in some cases of indium, thallium and europium metals. All these studies hav