Titlebook: Electron Paramagnetic Resonance Spectroscopy; Fundamentals Patrick Bertrand Textbook 2020 Springer Nature Switzerland AG 2020 Electron Para

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https://doi.org/10.1007/978-3-8348-9032-0ing equivalent operators for every Kramers doublet, and the results are used to analyze experimental data. The magnetic characteristics of actinide ions are then described, followed by a comparison of spectra for complexes of trivalent rare-earth and actinide cations.

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on experimental application.Features a progressive and rigorAlthough originally invented and employed by physicists, electron paramagnetic resonance (EPR) spectroscopy has proven to be a very efficient technique for studying a wide range of phenomena in many fields, such as chemistry, biochemistry,

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,Nassbereiche in privaten B?dern (neu),ed, highlighting their diversity. The principle of an EPR experiment is presented, along with a general expression for the absorption signal at thermal equilibrium. Finally, the functioning of a continuous-wave spectrometer is also explained.

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Verformungsberechnung von Holztragwerken,ngle crystals, frozen solutions, and powders. The various contributions to the hyperfine . matrix are then introduced, and the main features of the spectrum in the presence of anisotropic hyperfine interactions are calculated. The effect of molecular motion on the shape of the spectrum is considered.

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https://doi.org/10.1007/3-540-35026-8 phenomena are then described, leading to an expression for the absorption signal from a saturated line. Finally, the various spin-lattice relaxation processes are described, emphasizing the importance of spin-lattice relaxation in EPR spectroscopy.

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https://doi.org/10.1007/978-3-642-56943-2ssion of the progressive saturation and relaxation broadening methods that can be used to determine the spin-lattice relaxation time .. A section is devoted to the numerical simulation of spectra, and another to the use of magnetic-field and intensity standards in EPR spectroscopy.