Titlebook: Dynamics in Geometrical Confinement; Friedrich Kremer Book 2014 Springer International Publishing Switzerland 2014 1–, 2– and 3-dimensiona

寒冷

Rotational and Translational Diffusion of Ionic Liquids in Silica Nanopores,the observation that silanization of silica nanopores results in significant increase of the effective diffusion coefficient, which approaches the value for the bulk liquid. For a different IL ([BMIM] [BF.]), it is observed that ionic mobility at lower temperatures is enhanced by more than two decad

overture

Polymer Nanofluidics by Broadband Dielectric Spectroscopy, we show that different aspects of the flow process of polymers in cylindrical nanopores can be investigated by means of Broadband Dielectric Spectroscopy, using a recently developed experimental approach, which employs highly ordered nanoporous media as nanofluidics cell. No significant shifts in t

headlong

異端

Molecular Mobility and Phase Transformations of Several Low Molecular Weight Glass Formers Confined which is taken as a finite size effect. Concerning the bulk-like process, assigned to the glassy dynamics of the molecules in the middle of the pore, the confinement effect becomes stronger depending on the material as follows: (1) Triton X-100, undergoing almost no change in the glass transition t

Cupidity

Fulminate

入伍儀式

Dynamic Calorimetric Glass Transition in Thin Polymer Films, combining various kinds of calorimeters. This broad dynamic range, akin to broadband dielectric spectroscopy, is significantly important for the study of confinement effects. Varying the frequency allows to change the corresponding length scale of the probed segmental dynamics. In a relaxation map,

反叛者

Equilibrium and Out-of-Equilibrium Dynamics in Confined Polymers and Other Glass Forming Systems byetermination of the different aspects of glassy dynamics in confinement, that is, the equilibrium dynamics in terms of the rate of spontaneous fluctuations as probed by experiments where a perturbation in the linear regime is applied, on the one hand, and the out-of-equilibrium dynamics in terms of

inculpate

Dielectric Relaxation of a Polybutadiene Melt at a Crystalline Graphite Surface: Atomistic Moleculao in confined situations. A chemically realistic Molecular Dynamics simulation, in which all information about molecular motions is available, can shed light onto the questions of heterogeneity and anisotropy of the underlying molecular relaxation processes which lead to the ensemble averaged experi

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